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  <xsd:element name="WeightedAverageNumberOfAmericanDepositorySharesOutstandingAbstract" id="nio_WeightedAverageNumberOfAmericanDepositorySharesOutstandingAbstract" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="ManufacturingInCollaborationWithJacAbstract" id="nio_ManufacturingInCollaborationWithJacAbstract" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="ScheduleOfEstimateUsefulLifeOfPropertyPlantAndEquipmentTableTextBlock" id="nio_ScheduleOfEstimateUsefulLifeOfPropertyPlantAndEquipmentTableTextBlock" type="dtr-types:textBlockItemType" abstract="false" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="ShanghaiNioSalesAndServicesCoLtdMember" id="nio_ShanghaiNioSalesAndServicesCoLtdMember" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="NumberOfShareHeldByVariableInterestEntities" id="nio_NumberOfShareHeldByVariableInterestEntities" type="xbrli:sharesItemType" abstract="false" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="SummaryOfSignificantAccountingPoliciesTable" id="nio_SummaryOfSignificantAccountingPoliciesTable" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrldt:hypercubeItem" />
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  <xsd:element name="PayablesForPurchaseOfPropertyAndEquipmentCurrent" id="nio_PayablesForPurchaseOfPropertyAndEquipmentCurrent" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="instant" xbrli:balance="credit" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="DeferredGovernmentGrantsNoncurrent" id="nio_DeferredGovernmentGrantsNoncurrent" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="instant" xbrli:balance="credit" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="ResearchAndDevelopmentExpenseEmployeeCompensation" id="nio_ResearchAndDevelopmentExpenseEmployeeCompensation" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ResearchAndDevelopmentExpenseDesignAndDevelopment" id="nio_ResearchAndDevelopmentExpenseDesignAndDevelopment" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ResearchAndDevelopmentExpenseTravelExpenses" id="nio_ResearchAndDevelopmentExpenseTravelExpenses" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ResearchAndDevelopmentExpenseDepreciationAndAmortizationExpenses" id="nio_ResearchAndDevelopmentExpenseDepreciationAndAmortizationExpenses" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ResearchAndDevelopmentExpenseRentalAndRelatedExpenses" id="nio_ResearchAndDevelopmentExpenseRentalAndRelatedExpenses" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element name="DepreciationAndAmortizationExpenses" id="nio_DepreciationAndAmortizationExpenses" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
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  <xsd:element id="nio_ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExpectedForfeitureRatePostVesting" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExpectedForfeitureRatePostVesting" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
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  <xsd:element id="nio_RevenueStandAloneFairValueAsPercentageOfGrossSellingPrice" name="RevenueStandAloneFairValueAsPercentageOfGrossSellingPrice" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_CashCashEquivalentsAndRestrictedCashSubjectToConvertibilityRestrictions" name="CashCashEquivalentsAndRestrictedCashSubjectToConvertibilityRestrictions" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_AccrualsAndOtherCurrentLiabilitiesDisclosureTextBlock" name="AccrualsAndOtherCurrentLiabilitiesDisclosureTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_RevenueRemainingPerformanceObligationIncentives" name="RevenueRemainingPerformanceObligationIncentives" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AdvanceFromCustomers" name="AdvanceFromCustomers" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
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  <xsd:element id="nio_ContractWithCustomerLiabilityAndOtherDeferredRevenueDisclosureTextBlock" name="ContractWithCustomerLiabilityAndOtherDeferredRevenueDisclosureTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
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  <xsd:element id="nio_DeferredItemsNoncurrent" name="DeferredItemsNoncurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ConvenienceTranslationPolicyTextBlock" name="ConvenienceTranslationPolicyTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_DebtInstrumentTrancheAxis" name="DebtInstrumentTrancheAxis" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrldt:dimensionItem" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_DebtInstrumentTrancheDomain" name="DebtInstrumentTrancheDomain" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_PropertyAndEquipmentUnderCapitalExpenditure" name="PropertyAndEquipmentUnderCapitalExpenditure" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_LeaseholdImprovementsUnderCapitalExpenditure" name="LeaseholdImprovementsUnderCapitalExpenditure" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_CapitalExpendituresContractedButNotRecognized" name="CapitalExpendituresContractedButNotRecognized" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_ContractWithCustomerLiabilityAdditions" name="ContractWithCustomerLiabilityAdditions" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_IncreaseAndDecreaseOperatingLeaseLiability" name="IncreaseAndDecreaseOperatingLeaseLiability" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_AccumulatedImpairmentPropertyPlantAndEquipment" name="AccumulatedImpairmentPropertyPlantAndEquipment" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AdditionalConvertibleNotesPayable" name="AdditionalConvertibleNotesPayable" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_OtherLiabilityNonCurrent" name="OtherLiabilityNonCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ScheduleOfLesseeLeaseDescriptionTableTextBlock" name="ScheduleOfLesseeLeaseDescriptionTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_ProceedsFromSaleOfRawMaterialPropertyAndEquipmentToRelatedParty" name="ProceedsFromSaleOfRawMaterialPropertyAndEquipmentToRelatedParty" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_InventoryWriteDowns" name="InventoryWriteDowns" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_AmortizationOfRightOfUseAssets" name="AmortizationOfRightOfUseAssets" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_TotalCashConsideration" name="TotalCashConsideration" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_NioAnhuiHoldingLtdMember" name="NioAnhuiHoldingLtdMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_StrategicInvestorsMember" name="StrategicInvestorsMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioHoldingCoLtdMember" name="NioHoldingCoLtdMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_AccountsAndFinancingReceivableAllowanceForCreditLossCurrent" name="AccountsAndFinancingReceivableAllowanceForCreditLossCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AccountsAndFinancingReceivableAllowanceForCreditLossNoncurrent" name="AccountsAndFinancingReceivableAllowanceForCreditLossNoncurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AccountsAndFinancingReceivableCreditLossExpenseReversal" name="AccountsAndFinancingReceivableCreditLossExpenseReversal" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_PeriodToSubmitApplicationForQualifiedInitialPublicOffering" name="PeriodToSubmitApplicationForQualifiedInitialPublicOffering" nillable="true" type="xbrli:durationItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_PeriodToCompleteQualifiedInitialPublicOffering" name="PeriodToCompleteQualifiedInitialPublicOffering" nillable="true" type="xbrli:durationItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_RedeemableNoncontrollingInterestAnnualInterestRate" name="RedeemableNoncontrollingInterestAnnualInterestRate" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_OperatingLossExpirationYearAxis" name="OperatingLossExpirationYearAxis" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrldt:dimensionItem" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_OperatingLossExpirationYearDomain" name="OperatingLossExpirationYearDomain" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_TradeAndNotesPayableCurrent" name="TradeAndNotesPayableCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ProceedsFromContributedCapitalRedeemableNonControllingInterests" name="ProceedsFromContributedCapitalRedeemableNonControllingInterests" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_ConvertibleSeniorNotesDue2026Member" name="ConvertibleSeniorNotesDue2026Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
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  <xsd:element id="nio_XunjieEnergyWuhanCo.Ltd.Member" name="XunjieEnergyWuhanCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_ConvertibleSeniorNotesDue2024Member" name="ConvertibleSeniorNotesDue2024Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_RevenueFromSalesOfGoods" name="RevenueFromSalesOfGoods" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_ReceivablesFromThirdPartyOnlinePaymentServiceVendors" name="ReceivablesFromThirdPartyOnlinePaymentServiceVendors" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_ChargingAndBatterySwapEquipmentMember" name="ChargingAndBatterySwapEquipmentMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_LongTermInvestmentsTextBlock" name="LongTermInvestmentsTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_LongTermInvestmentTableTextBlock" name="LongTermInvestmentTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_PercentageOfIndirectInterestInTotalPaidInCapital" name="PercentageOfIndirectInterestInTotalPaidInCapital" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_ShortTermBankBorrowingsCollateralAmountShortTermInvestments" name="ShortTermBankBorrowingsCollateralAmountShortTermInvestments" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_ShareCapitalClassToBeDeterminedNumberOfSharesAuthorized" name="ShareCapitalClassToBeDeterminedNumberOfSharesAuthorized" nillable="true" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_NioAutomobileAnhuiCo.Ltd.Member" name="NioAutomobileAnhuiCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioAutomobileTechnologyCo.Member" name="NioAutomobileTechnologyCo.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioFinancialLeasingCo.Ltd.Member" name="NioFinancialLeasingCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_PercentageOfPrincipalAmountOfNotesToBeRepurchasedForRepurchasePrice" name="PercentageOfPrincipalAmountOfNotesToBeRepurchasedForRepurchasePrice" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_AtMarketEquityOfferingProgramMember" name="AtMarketEquityOfferingProgramMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NumberOfOrdinarySharesInEachAds" name="NumberOfOrdinarySharesInEachAds" nillable="true" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_DebtInstrumentConversionPremium" name="DebtInstrumentConversionPremium" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_CappedCallTransactionsAndZeroStrikeCallTransactionsMember" name="CappedCallTransactionsAndZeroStrikeCallTransactionsMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_SettlementForCallOptionsValue" name="SettlementForCallOptionsValue" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_SettlementForCallOptionsShares" name="SettlementForCallOptionsShares" nillable="true" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_CurrentExpectedCreditLossesAbstract" name="CurrentExpectedCreditLossesAbstract" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_RentalAndRelatedExpenses" name="RentalAndRelatedExpenses" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_AccretionOnRedeemableNonControllingInterestsToRedemptionValue" name="AccretionOnRedeemableNonControllingInterestsToRedemptionValue" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_CustomerMember" name="CustomerMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_SupplierMember" name="SupplierMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element name="NeuBatteryAssetCo.Ltd.BacCaymanMember" id="nio_NeuBatteryAssetCo.Ltd.BacCaymanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NeuBatteryAssetHongKongCo.limitedBacHkMember" id="nio_NeuBatteryAssetHongKongCo.limitedBacHkMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="InstantPowerEuropeB.v.BacNlMember" id="nio_InstantPowerEuropeB.v.BacNlMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioNextevEuropeHoldingB.v.NioNlMember" id="nio_NioNextevEuropeHoldingB.v.NioNlMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="IncreaseDecreaseInInvestmentIncome" id="nio_IncreaseDecreaseInInvestmentIncome" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="WeightedAverageNumberOfAmericanDepositorySharesOutstandingBasic" id="nio_WeightedAverageNumberOfAmericanDepositorySharesOutstandingBasic" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="WeightedAverageNumberOfAmericanDepositorySharesOutstandingDiluted" id="nio_WeightedAverageNumberOfAmericanDepositorySharesOutstandingDiluted" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EarningsLossPerAmericanDepositoryShareBasic" id="nio_EarningsLossPerAmericanDepositoryShareBasic" type="dtr-types:perShareItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EarningsLossPerAmericanDepositoryShareDiluted" id="nio_EarningsLossPerAmericanDepositoryShareDiluted" type="dtr-types:perShareItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LiquidationMember" id="nio_LiquidationMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RedemptionMember" id="nio_RedemptionMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="MeasurementInputProbabilityMember" id="nio_MeasurementInputProbabilityMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExerciseMultiple" id="nio_ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExerciseMultiple" type="xbrli:decimalItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EquitySecuritiesWithoutReadilyDeterminableFairValueInitialCost" id="nio_EquitySecuritiesWithoutReadilyDeterminableFairValueInitialCost" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="PrivateCompanyMember" id="nio_PrivateCompanyMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="InitialPublicOfferingScenarioMember" id="nio_InitialPublicOfferingScenarioMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ScheduleOfBorrowingsTable" id="nio_ScheduleOfBorrowingsTable" type="xbrli:stringItemType" substitutionGroup="xbrldt:hypercubeItem" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ScheduleOfBorrowingsLineItems" id="nio_ScheduleOfBorrowingsLineItems" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ImpairmentOfInvestments1" id="nio_ImpairmentOfInvestments1" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="JianglaiAdvancedManufacturingTechnologyAnhuiCo.Ltd.Member" id="nio_JianglaiAdvancedManufacturingTechnologyAnhuiCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="HefeiChuangWeiInformationConsultationCo.LtdMember" id="nio_HefeiChuangWeiInformationConsultationCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturityJune2025Member" id="nio_LoanAgreementWithBankOfShanghaiMaturityJune2025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithChinaConstructionBankMaturityJuly2029OneMember" id="nio_LoanAgreementWithChinaConstructionBankMaturityJuly2029OneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029Member" id="nio_LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithChinaConstructionBankMaturityJuly2029TwoMember" id="nio_LoanAgreementWithChinaConstructionBankMaturityJuly2029TwoMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LettersOfGuaranteeMember" id="nio_LettersOfGuaranteeMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SubsidiaryAdopted2021ShareIncentivePlanMember" id="nio_SubsidiaryAdopted2021ShareIncentivePlanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioAiTechnologyLimitedHongKongMember" id="nio_NioAiTechnologyLimitedHongKongMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AnhuiNioAutonomousDrivingTechnologyCoMember" id="nio_AnhuiNioAutonomousDrivingTechnologyCoMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RedeemableNonControllingInterestsTextBlock" id="nio_RedeemableNonControllingInterestsTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="PrepaymentsAndOtherCurrentAssetsAllowanceForCreditLossCurrent" id="nio_PrepaymentsAndOtherCurrentAssetsAllowanceForCreditLossCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="OtherNonCurrentAssetsNetAllowanceForCreditLossNonCurrent" id="nio_OtherNonCurrentAssetsNetAllowanceForCreditLossNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="OtherAssetsNoncurrentGross" id="nio_OtherAssetsNoncurrentGross" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="GrossPrepaidExpenseAndOtherAssetsCurrent" id="nio_GrossPrepaidExpenseAndOtherAssetsCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="EquitySecuritiesWithoutReadilyDeterminableFairValueYearToYearChangeInValue" id="nio_EquitySecuritiesWithoutReadilyDeterminableFairValueYearToYearChangeInValue" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="NioCo.LtdMember" id="nio_NioCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioUsaIncMember" id="nio_NioUsaIncMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="XptJiangsuInvestmentCo.Ltd.Member" id="nio_XptJiangsuInvestmentCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioAiTechnologyLimitedNioAiTechnologyMember" id="nio_NioAiTechnologyLimitedNioAiTechnologyMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ConsolidationItems1Axis" id="nio_ConsolidationItems1Axis" type="xbrli:stringItemType" substitutionGroup="xbrldt:dimensionItem" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ConsolidationItems1Domain" id="nio_ConsolidationItems1Domain" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="BeijingWelionNewEnergyTechnologyCo.LtdMember" id="nio_BeijingWelionNewEnergyTechnologyCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SubscriptionVehiclesMember" id="nio_SubscriptionVehiclesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DebtSecuritiesTradingNonCurrent" id="nio_DebtSecuritiesTradingNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="CyvnEntitiesMember" id="nio_CyvnEntitiesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="EquitySecuritiesWithFairValueOption" id="nio_EquitySecuritiesWithFairValueOption" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ConvertibleSeniorNotesDue2029Member" id="nio_ConvertibleSeniorNotesDue2029Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ConvertibleSeniorNotesDue2030Member" id="nio_ConvertibleSeniorNotesDue2030Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithChinaConstructionBankMaturityJuly2029ThreeMember" id="nio_LoanAgreementWithChinaConstructionBankMaturityJuly2029ThreeMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturitySeptember2026Member" id="nio_LoanAgreementWithBankOfShanghaiMaturitySeptember2026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NewHorizonBVMember" id="nio_NewHorizonBVMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ConvertibleSeniorNotesDue2029And2030Member" id="nio_ConvertibleSeniorNotesDue2029And2030Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PrepaymentsForLongTermAssetsNonCurrent" id="nio_PrepaymentsForLongTermAssetsNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="NioSoftwareTechnologyShanghaiCo.LtdShstMember" id="nio_NioSoftwareTechnologyShanghaiCo.LtdShstMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DirectOwnershipPercentageInSubsidiaries" id="nio_DirectOwnershipPercentageInSubsidiaries" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" />
  <xsd:element name="IncreaseDecreaseInDueToRelatedPartiesNonCurrent" id="nio_IncreaseDecreaseInDueToRelatedPartiesNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="WuhanWeinengBatteryAssetsCo.LtdAndItsSubsidiariesMember" id="nio_WuhanWeinengBatteryAssetsCo.LtdAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="WuhanWeinengBatteryAssetsCo.Ltd.AndItsSubsidiaryMember" id="nio_WuhanWeinengBatteryAssetsCo.Ltd.AndItsSubsidiaryMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ClassOfWarrantOrRightAmountOfSecuritiesCalledByWarrants" id="nio_ClassOfWarrantOrRightAmountOfSecuritiesCalledByWarrants" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="PeriodOfRightToRequestForRedemptionOfEquityInterest" id="nio_PeriodOfRightToRequestForRedemptionOfEquityInterest" type="xbrli:durationItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LoanAgreementWithChinaConstructionBankMaturityJanuary2031Member" id="nio_LoanAgreementWithChinaConstructionBankMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJanuary2031Member" id="nio_LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithChinaMinshengBankMaturityJanuary2031Member" id="nio_LoanAgreementWithChinaMinshengBankMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithAgriculturalBankOfChinaMaturityJanuary2031Member" id="nio_LoanAgreementWithAgriculturalBankOfChinaMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturityJanuary2027Member" id="nio_LoanAgreementWithBankOfShanghaiMaturityJanuary2027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturityFebruary2027Member" id="nio_LoanAgreementWithBankOfShanghaiMaturityFebruary2027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DebtSecuritiesAvailableForSaleImpairmentLoss" id="nio_DebtSecuritiesAvailableForSaleImpairmentLoss" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ScheduleOfOtherNonCurrentLiabilitiesTable" id="nio_ScheduleOfOtherNonCurrentLiabilitiesTable" type="xbrli:stringItemType" substitutionGroup="xbrldt:hypercubeItem" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PayablesToBatteryAsServiceUsersNoncurrent" id="nio_PayablesToBatteryAsServiceUsersNoncurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="EquityMethodInvestmentsAbstract" id="nio_EquityMethodInvestmentsAbstract" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="RetainedAssetBackedSecuritiesAbstract" id="nio_RetainedAssetBackedSecuritiesAbstract" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="BlueHorizonLimitedAndItsSubsidiariesMember" id="nio_BlueHorizonLimitedAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="StockIncentivePlan20162017StockIncentivePlan2018StockIncentivePlanAnd2024StockIncentivePlanMember" id="nio_StockIncentivePlan20162017StockIncentivePlan2018StockIncentivePlanAnd2024StockIncentivePlanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ScheduleOfOtherNonCurrentLiabilitiesLineItems" id="nio_ScheduleOfOtherNonCurrentLiabilitiesLineItems" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CurrentLiabilitiesNet" id="nio_CurrentLiabilitiesNet" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CashCashEquivalentsShortTermInvestmentsAndLongTermDeposits" id="nio_CashCashEquivalentsShortTermInvestmentsAndLongTermDeposits" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="CurrentBorrowingsAndCurrentPortionOfNoncurrentBorrowings" id="nio_CurrentBorrowingsAndCurrentPortionOfNoncurrentBorrowings" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ChargingAndPowerSwapInfrastructureMember" id="nio_ChargingAndPowerSwapInfrastructureMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="TreasuryStockValueExchangeOfConvertibleSecuritiesToOrdinaryShares" id="nio_TreasuryStockValueExchangeOfConvertibleSecuritiesToOrdinaryShares" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TianjinTengyiInformationTechnologyCo.Ltd.Member" id="nio_TianjinTengyiInformationTechnologyCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioStockIncentivePlansFrom2015To2024Member" id="nio_NioStockIncentivePlansFrom2015To2024Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PurchaseOfServiceMember" id="nio_PurchaseOfServiceMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PurchaseOfRawMaterialOrPropertyPlantAndEquipmentMember" id="nio_PurchaseOfRawMaterialOrPropertyPlantAndEquipmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PrivateFundsAndEntitiesMember" id="nio_PrivateFundsAndEntitiesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ShortTermBorrowingsAtDecember2024Member" id="nio_ShortTermBorrowingsAtDecember2024Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AmountPayableToBaasUsersCurrentPortion" id="nio_AmountPayableToBaasUsersCurrentPortion" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="DebtInstrumentPrincipalAmountDenominationForConversionIntoCommonStock" id="nio_DebtInstrumentPrincipalAmountDenominationForConversionIntoCommonStock" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029OneMember" id="nio_LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029OneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AllowanceForExpectedCreditLosses" id="nio_AllowanceForExpectedCreditLosses" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="SharesIssuedValueShareBasedPaymentArrangementRestrictedSharesAndShareOptions" id="nio_SharesIssuedValueShareBasedPaymentArrangementRestrictedSharesAndShareOptions" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="SharesIssuedSharesShareBasedPaymentArrangementRestrictedSharesAndShareOptions" id="nio_SharesIssuedSharesShareBasedPaymentArrangementRestrictedSharesAndShareOptions" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="AssetTransferAgreementsConsideration" id="nio_AssetTransferAgreementsConsideration" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ShortTermBorrowingsAtJune2025Member" id="nio_ShortTermBorrowingsAtJune2025Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ConvertibleSeniorNotesDue2026And2027Member" id="nio_ConvertibleSeniorNotesDue2026And2027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="MclarenGroupHoldingsLimitedAndItsSubsidiariesMember" id="nio_MclarenGroupHoldingsLimitedAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="VtaTechnologyIncAndItsSubsidiariesMember" id="nio_VtaTechnologyIncAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="EquityMethodAdditionalInvestments" id="nio_EquityMethodAdditionalInvestments" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="SaleAndLeasebackArrangementsSettled" id="nio_SaleAndLeasebackArrangementsSettled" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
</xsd:schema>
