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  <xsd:element name="ResearchAndDevelopmentExpenseOthers" id="nio_ResearchAndDevelopmentExpenseOthers" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="DepreciationAndAmortizationExpenses" id="nio_DepreciationAndAmortizationExpenses" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="duration" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ShareCapitalValueAuthorized" id="nio_ShareCapitalValueAuthorized" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="instant" xbrli:balance="credit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ShareCapitalSharesAuthorized" id="nio_ShareCapitalSharesAuthorized" type="xbrli:sharesItemType" abstract="false" xbrli:periodType="instant" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element id="nio_ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExpectedForfeitureRatePostVesting" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsExpectedForfeitureRatePostVesting" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element name="IncomeTaxTable" id="nio_IncomeTaxTable" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrldt:hypercubeItem" />
  <xsd:element name="IncomeTaxLineItems" id="nio_IncomeTaxLineItems" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="DeferredTaxAssetsAdvertisingExpensesInExcessOfDeductionLimit" id="nio_DeferredTaxAssetsAdvertisingExpensesInExcessOfDeductionLimit" type="xbrli:monetaryItemType" abstract="false" xbrli:periodType="instant" xbrli:balance="debit" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="DeferredTaxAssetValuationAllowanceRollForward" id="nio_DeferredTaxAssetValuationAllowanceRollForward" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="PercentageOfWithholdingTaxForForeignInvestorsNonResidentEnterprises" id="nio_PercentageOfWithholdingTaxForForeignInvestorsNonResidentEnterprises" type="dtr-types:percentItemType" abstract="false" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="PercentageOfWithholdingTaxForResidentEnterprise" id="nio_PercentageOfWithholdingTaxForResidentEnterprise" type="dtr-types:percentItemType" abstract="false" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="AdditionalPercentageOfQualifiedResearchAndDevelopmentExpensesClaimedInAnnualFiling" id="nio_AdditionalPercentageOfQualifiedResearchAndDevelopmentExpensesClaimedInAnnualFiling" type="dtr-types:percentItemType" abstract="false" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="DenominatorAbstract" id="nio_DenominatorAbstract" type="xbrli:stringItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="ShanghaiWeishangBusinessConsultingCo.Ltd.Member" id="nio_ShanghaiWeishangBusinessConsultingCo.Ltd.Member" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="NanjingWeibangTransmissionTechnologyCo.Ltd.Member" id="nio_NanjingWeibangTransmissionTechnologyCo.Ltd.Member" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="NingboMeishanFreeTradePortZoneWeilanInvestmentCo.Ltd.Member" id="nio_NingboMeishanFreeTradePortZoneWeilanInvestmentCo.Ltd.Member" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element name="KunshanSiwopuIntelligentEquipmentCo.Ltd.Member" id="nio_KunshanSiwopuIntelligentEquipmentCo.Ltd.Member" type="dtr-types:domainItemType" abstract="true" xbrli:periodType="duration" nillable="true" substitutionGroup="xbrli:item" />
  <xsd:element id="nio_IncentivesPerformanceObligationRevenueRecordedAsContractLiability" name="IncentivesPerformanceObligationRevenueRecordedAsContractLiability" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_IncentivesPerformanceObligationAmountChargedToSellingAndMarketingExpenses" name="IncentivesPerformanceObligationAmountChargedToSellingAndMarketingExpenses" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_RevenueStandAloneFairValueAsPercentageOfGrossSellingPrice" name="RevenueStandAloneFairValueAsPercentageOfGrossSellingPrice" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_CashCashEquivalentsAndRestrictedCashSubjectToConvertibilityRestrictions" name="CashCashEquivalentsAndRestrictedCashSubjectToConvertibilityRestrictions" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_AccrualsAndOtherCurrentLiabilitiesDisclosureTextBlock" name="AccrualsAndOtherCurrentLiabilitiesDisclosureTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear1" name="OperatingLossCarryforwardsExpiringYear1" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear2" name="OperatingLossCarryforwardsExpiringYear2" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear3" name="OperatingLossCarryforwardsExpiringYear3" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear4" name="OperatingLossCarryforwardsExpiringYear4" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear5" name="OperatingLossCarryforwardsExpiringYear5" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsNoExpiration" name="OperatingLossCarryforwardsNoExpiration" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpirationPeriod" name="OperatingLossCarryforwardsExpirationPeriod" nillable="true" type="xbrli:durationItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_RevenueRemainingPerformanceObligationIncentives" name="RevenueRemainingPerformanceObligationIncentives" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AdvanceFromCustomers" name="AdvanceFromCustomers" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_UnrecognizedDeferredRevenue" name="UnrecognizedDeferredRevenue" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ContractWithCustomerLiabilityAndOtherDeferredRevenueDisclosureTextBlock" name="ContractWithCustomerLiabilityAndOtherDeferredRevenueDisclosureTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_DeferredItemsCurrent" name="DeferredItemsCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_DeferredItemsNoncurrent" name="DeferredItemsNoncurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ConvenienceTranslationPolicyTextBlock" name="ConvenienceTranslationPolicyTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_LandUseRightsNetAbstract" name="LandUseRightsNetAbstract" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_LandUseRightsGross" name="LandUseRightsGross" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_AccumulatedAmortizationOnLandUseRights" name="AccumulatedAmortizationOnLandUseRights" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_DebtInstrumentTrancheAxis" name="DebtInstrumentTrancheAxis" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrldt:dimensionItem" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_DebtInstrumentTrancheDomain" name="DebtInstrumentTrancheDomain" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_ScheduleOfLandUseRightsNetTableTextBlock" name="ScheduleOfLandUseRightsNetTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_PropertyAndEquipmentUnderCapitalExpenditure" name="PropertyAndEquipmentUnderCapitalExpenditure" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_LeaseholdImprovementsUnderCapitalExpenditure" name="LeaseholdImprovementsUnderCapitalExpenditure" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_CapitalExpendituresContractedButNotRecognized" name="CapitalExpendituresContractedButNotRecognized" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_ContractWithCustomerLiabilityAdditions" name="ContractWithCustomerLiabilityAdditions" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_IncreaseAndDecreaseOperatingLeaseLiability" name="IncreaseAndDecreaseOperatingLeaseLiability" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_AccumulatedImpairmentPropertyPlantAndEquipment" name="AccumulatedImpairmentPropertyPlantAndEquipment" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AdditionalConvertibleNotesPayable" name="AdditionalConvertibleNotesPayable" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_OtherLiabilityNonCurrent" name="OtherLiabilityNonCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ScheduleOfLesseeLeaseDescriptionTableTextBlock" name="ScheduleOfLesseeLeaseDescriptionTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_ProceedsFromSaleOfRawMaterialPropertyAndEquipmentToRelatedParty" name="ProceedsFromSaleOfRawMaterialPropertyAndEquipmentToRelatedParty" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_HuangRiverInvestmentLimitedMember" name="HuangRiverInvestmentLimitedMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_InventoryWriteDowns" name="InventoryWriteDowns" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_AmortizationExpensesLandUseRights" name="AmortizationExpensesLandUseRights" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_TaxAuthoritiesInHongKongMember" name="TaxAuthoritiesInHongKongMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_AmortizationOfRightOfUseAssets" name="AmortizationOfRightOfUseAssets" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_TotalCashConsideration" name="TotalCashConsideration" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_NioAnhuiHoldingLtdMember" name="NioAnhuiHoldingLtdMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_StrategicInvestorsMember" name="StrategicInvestorsMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioHoldingCoLtdMember" name="NioHoldingCoLtdMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_AccountsAndFinancingReceivableAllowanceForCreditLossCurrent" name="AccountsAndFinancingReceivableAllowanceForCreditLossCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AccountsAndFinancingReceivableAllowanceForCreditLossNoncurrent" name="AccountsAndFinancingReceivableAllowanceForCreditLossNoncurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_AccountsAndFinancingReceivableCreditLossExpenseReversal" name="AccountsAndFinancingReceivableCreditLossExpenseReversal" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_PeriodToSubmitApplicationForQualifiedInitialPublicOffering" name="PeriodToSubmitApplicationForQualifiedInitialPublicOffering" nillable="true" type="xbrli:durationItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_PeriodToCompleteQualifiedInitialPublicOffering" name="PeriodToCompleteQualifiedInitialPublicOffering" nillable="true" type="xbrli:durationItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_RedeemableNoncontrollingInterestAnnualInterestRate" name="RedeemableNoncontrollingInterestAnnualInterestRate" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_OperatingLossExpirationYearAxis" name="OperatingLossExpirationYearAxis" nillable="true" type="xbrli:stringItemType" substitutionGroup="xbrldt:dimensionItem" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_OperatingLossExpirationYearDomain" name="OperatingLossExpirationYearDomain" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_TradeAndNotesPayableCurrent" name="TradeAndNotesPayableCurrent" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ProceedsFromContributedCapitalRedeemableNonControllingInterests" name="ProceedsFromContributedCapitalRedeemableNonControllingInterests" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_ConvertibleSeniorNotesDue2026Member" name="ConvertibleSeniorNotesDue2026Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_ConvertibleSeniorNotesDue2027Member" name="ConvertibleSeniorNotesDue2027Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_XunjieEnergyWuhanCo.Ltd.Member" name="XunjieEnergyWuhanCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_ConvertibleSeniorNotesDue2024Member" name="ConvertibleSeniorNotesDue2024Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_LesseeLeaseLiabilityMaturityTableTextBlock" name="LesseeLeaseLiabilityMaturityTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_LesseeOperatingLeaseLiabilityToBePaidYearSix" name="LesseeOperatingLeaseLiabilityToBePaidYearSix" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_LesseeOperatingLeaseLiabilityToBePaidAfterYearSix" name="LesseeOperatingLeaseLiabilityToBePaidAfterYearSix" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_DeferredTaxAssetsUnrealizedCurrencyGainsLosses" name="DeferredTaxAssetsUnrealizedCurrencyGainsLosses" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_RevenueFromSalesOfGoods" name="RevenueFromSalesOfGoods" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_FinanceLeaseLiabilityPaymentsDueYearSix" name="FinanceLeaseLiabilityPaymentsDueYearSix" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
  <xsd:element id="nio_ChargingAndBatterySwapEquipmentMember" name="ChargingAndBatterySwapEquipmentMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_LongTermInvestmentsTextBlock" name="LongTermInvestmentsTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_LongTermInvestmentTableTextBlock" name="LongTermInvestmentTableTextBlock" nillable="true" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_WuhanWeinengBatteryAssetCo.Ltd.Member" name="WuhanWeinengBatteryAssetCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_OtherThirdPartyInvestorsMember" name="OtherThirdPartyInvestorsMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NumberOfThirdPartyInvestors" name="NumberOfThirdPartyInvestors" nillable="true" type="xbrli:integerItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_AdditionalInvestmentInEquitySecurities" name="AdditionalInvestmentInEquitySecurities" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
  <xsd:element id="nio_PercentageOfIndirectInterestInTotalPaidInCapital" name="PercentageOfIndirectInterestInTotalPaidInCapital" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear6" name="OperatingLossCarryforwardsExpiringYear6" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear7" name="OperatingLossCarryforwardsExpiringYear7" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear8" name="OperatingLossCarryforwardsExpiringYear8" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_OperatingLossCarryforwardsExpiringYear9" name="OperatingLossCarryforwardsExpiringYear9" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_RemainingTaxableIncomeMember" name="RemainingTaxableIncomeMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_ShortTermBankBorrowingsCollateralAmountShortTermInvestments" name="ShortTermBankBorrowingsCollateralAmountShortTermInvestments" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="debit" />
  <xsd:element id="nio_ShareCapitalClassToBeDeterminedNumberOfSharesAuthorized" name="ShareCapitalClassToBeDeterminedNumberOfSharesAuthorized" nillable="true" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_NioAutomobileAnhuiCo.Ltd.Member" name="NioAutomobileAnhuiCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioAutomobileTechnologyCo.Member" name="NioAutomobileTechnologyCo.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NioFinancialLeasingCo.Ltd.Member" name="NioFinancialLeasingCo.Ltd.Member" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_TradeAndNotesReceivableMember" name="TradeAndNotesReceivableMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_AmountsDueFromRelatedPartiesMember" name="AmountsDueFromRelatedPartiesMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_AccountsAndFinancingReceivableExpectedCreditLossRateCurrent" name="AccountsAndFinancingReceivableExpectedCreditLossRateCurrent" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_AccountsAndFinancingReceivableExpectedCreditLossRateNonCurrent" name="AccountsAndFinancingReceivableExpectedCreditLossRateNonCurrent" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_PercentageOfPrincipalAmountOfNotesToBeRepurchasedForRepurchasePrice" name="PercentageOfPrincipalAmountOfNotesToBeRepurchasedForRepurchasePrice" nillable="true" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_AtMarketEquityOfferingProgramMember" name="AtMarketEquityOfferingProgramMember" nillable="true" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" abstract="true" xbrli:periodType="duration" />
  <xsd:element id="nio_NumberOfOrdinarySharesInEachAds" name="NumberOfOrdinarySharesInEachAds" nillable="true" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" />
  <xsd:element id="nio_DebtInstrumentConversionPremium" name="DebtInstrumentConversionPremium" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="instant" xbrli:balance="credit" />
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  <xsd:element id="nio_RentalAndRelatedExpenses" name="RentalAndRelatedExpenses" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_AccretionOnRedeemableNonControllingInterestsToRedemptionValue" name="AccretionOnRedeemableNonControllingInterestsToRedemptionValue" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="debit" />
  <xsd:element id="nio_PaymentsToAcquireAvailableForSaleSecuritiesDebtContributionByCompany" name="PaymentsToAcquireAvailableForSaleSecuritiesDebtContributionByCompany" nillable="true" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" xbrli:periodType="duration" xbrli:balance="credit" />
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  <xsd:element name="NioAiTechnologyLimitedHongKongMember" id="nio_NioAiTechnologyLimitedHongKongMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
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  <xsd:element name="PrepaymentsAndOtherCurrentAssetsAllowanceForCreditLossCurrent" id="nio_PrepaymentsAndOtherCurrentAssetsAllowanceForCreditLossCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
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  <xsd:element name="BeijingWelionNewEnergyTechnologyCo.LtdMember" id="nio_BeijingWelionNewEnergyTechnologyCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SubscriptionVehiclesMember" id="nio_SubscriptionVehiclesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DebtSecuritiesTradingNonCurrent" id="nio_DebtSecuritiesTradingNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
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  <xsd:element name="OperatingLossCarryforwardsExpiringYear10" id="nio_OperatingLossCarryforwardsExpiringYear10" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
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  <xsd:element name="LoanAgreementWithChinaConstructionBankMaturityJuly2029ThreeMember" id="nio_LoanAgreementWithChinaConstructionBankMaturityJuly2029ThreeMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
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  <xsd:element name="WuhanWeinengBatteryAssetsCo.LtdAndItsSubsidiariesMember" id="nio_WuhanWeinengBatteryAssetsCo.LtdAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ClassOfWarrantOrRightAmountOfSecuritiesCalledByWarrants" id="nio_ClassOfWarrantOrRightAmountOfSecuritiesCalledByWarrants" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
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  <xsd:element name="LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJanuary2031Member" id="nio_LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithChinaMinshengBankMaturityJanuary2031Member" id="nio_LoanAgreementWithChinaMinshengBankMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithAgriculturalBankOfChinaMaturityJanuary2031Member" id="nio_LoanAgreementWithAgriculturalBankOfChinaMaturityJanuary2031Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturityJanuary2027Member" id="nio_LoanAgreementWithBankOfShanghaiMaturityJanuary2027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="LoanAgreementWithBankOfShanghaiMaturityFebruary2027Member" id="nio_LoanAgreementWithBankOfShanghaiMaturityFebruary2027Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DebtSecuritiesAvailableForSaleImpairmentLoss" id="nio_DebtSecuritiesAvailableForSaleImpairmentLoss" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ScheduleOfOtherNonCurrentLiabilitiesTable" id="nio_ScheduleOfOtherNonCurrentLiabilitiesTable" type="xbrli:stringItemType" substitutionGroup="xbrldt:hypercubeItem" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PayablesToBatteryAsServiceUsersNoncurrent" id="nio_PayablesToBatteryAsServiceUsersNoncurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="BlueHorizonLimitedAndItsSubsidiariesMember" id="nio_BlueHorizonLimitedAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="StockIncentivePlan20162017StockIncentivePlan2018StockIncentivePlanAnd2024StockIncentivePlanMember" id="nio_StockIncentivePlan20162017StockIncentivePlan2018StockIncentivePlanAnd2024StockIncentivePlanMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ScheduleOfOtherNonCurrentLiabilitiesLineItems" id="nio_ScheduleOfOtherNonCurrentLiabilitiesLineItems" type="xbrli:stringItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="JointVentureMember" id="nio_JointVentureMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AuthorizedShareCapital" id="nio_AuthorizedShareCapital" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CyvnHoldingLlcMember" id="nio_CyvnHoldingLlcMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="OtherComprehensiveIncomeLossDebtSecurityAvailableForSaleRecyclingOfUnrealizedGainLoss" id="nio_OtherComprehensiveIncomeLossDebtSecurityAvailableForSaleRecyclingOfUnrealizedGainLoss" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="CurrentLiabilitiesNet" id="nio_CurrentLiabilitiesNet" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CurrentBorrowingsAndCurrentPortionOfNoncurrentBorrowings" id="nio_CurrentBorrowingsAndCurrentPortionOfNoncurrentBorrowings" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ChargingAndPowerSwapInfrastructureMember" id="nio_ChargingAndPowerSwapInfrastructureMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="TreasuryStockValueExchangeOfConvertibleSecuritiesToOrdinaryShares" id="nio_TreasuryStockValueExchangeOfConvertibleSecuritiesToOrdinaryShares" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="TreasuryStockSharesExchangeOfConvertibleSecuritiesToOrdinaryShares" id="nio_TreasuryStockSharesExchangeOfConvertibleSecuritiesToOrdinaryShares" type="xbrli:sharesItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="InvestmentDeficitInSubsidiariesAndAffiliatesNonCurrent" id="nio_InvestmentDeficitInSubsidiariesAndAffiliatesNonCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="TianjinTengyiInformationTechnologyCo.Ltd.Member" id="nio_TianjinTengyiInformationTechnologyCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="NioStockIncentivePlansFrom2015To2024Member" id="nio_NioStockIncentivePlansFrom2015To2024Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ExchangeOfConvertibleSecuritiesWithCancellationOfTreasuryShares" id="nio_ExchangeOfConvertibleSecuritiesWithCancellationOfTreasuryShares" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="PurchaseOfServiceMember" id="nio_PurchaseOfServiceMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PurchaseOfRawMaterialOrPropertyPlantAndEquipmentMember" id="nio_PurchaseOfRawMaterialOrPropertyPlantAndEquipmentMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PrivateFundsAndEntitiesMember" id="nio_PrivateFundsAndEntitiesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ShortTermBorrowingsAtDecember2024Member" id="nio_ShortTermBorrowingsAtDecember2024Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="AmountPayableToBaasUsersCurrentPortion" id="nio_AmountPayableToBaasUsersCurrentPortion" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="DebtInstrumentPrincipalAmountDenominationForConversionIntoCommonStock" id="nio_DebtInstrumentPrincipalAmountDenominationForConversionIntoCommonStock" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029OneMember" id="nio_LoanAgreementWithIndustrialAndCommercialBankOfChinaMaturityJuly2029OneMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="CashCashEquivalentsRestrictedCashAndShortTermInvestments" id="nio_CashCashEquivalentsRestrictedCashAndShortTermInvestments" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AllowanceForExpectedCreditLosses" id="nio_AllowanceForExpectedCreditLosses" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="MclarenGroupHoldingsLimitedAndItsSubsidiariesMember" id="nio_MclarenGroupHoldingsLimitedAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="VtaTechnologyIncAndItsSubsidiariesMember" id="nio_VtaTechnologyIncAndItsSubsidiariesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SalesAndMarketingExpensesPolicyTextBlock" id="nio_SalesAndMarketingExpensesPolicyTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="LandUseRightsNetPolicyTextBlock" id="nio_LandUseRightsNetPolicyTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="PaymentsToAcquireEquityInvestments" id="nio_PaymentsToAcquireEquityInvestments" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ScheduleOfEstimateUsefulLifeOfIntangibleAssetsNetTableTextBlock" id="nio_ScheduleOfEstimateUsefulLifeOfIntangibleAssetsNetTableTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="HefeiChuangweiInformationConsultationCo.Ltd.Member" id="nio_HefeiChuangweiInformationConsultationCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="SalesAndLeasebackArrangementSettledThroughTransferOfControl" id="nio_SalesAndLeasebackArrangementSettledThroughTransferOfControl" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="EquitySecuritiesWithReadilyDeterminableFairValueImpairmentLossAnnualAmount" id="nio_EquitySecuritiesWithReadilyDeterminableFairValueImpairmentLossAnnualAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AdditionalInvestmentRightAmount" id="nio_AdditionalInvestmentRightAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtSecuritiesAvailableForSaleTaxEffectOfUnrealizedGainLoss" id="nio_DebtSecuritiesAvailableForSaleTaxEffectOfUnrealizedGainLoss" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtSecuritiesAvailableForSaleUnrealizedGainLossAttributableToNonControllingInterest" id="nio_DebtSecuritiesAvailableForSaleUnrealizedGainLossAttributableToNonControllingInterest" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="InvestmentInSubsidiaries" id="nio_InvestmentInSubsidiaries" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="AdditionalInvestmentInSubsidiaries" id="nio_AdditionalInvestmentInSubsidiaries" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="SubsidiaryEquityInvestmentAmount" id="nio_SubsidiaryEquityInvestmentAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="GenitechCo.LtdMember" id="nio_GenitechCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ThirdPartyOwnershipInterestPercentageInSubsidiary" id="nio_ThirdPartyOwnershipInterestPercentageInSubsidiary" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="ShareIncentivePlanOwnershipInterestPercentage" id="nio_ShareIncentivePlanOwnershipInterestPercentage" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NioIncentivePlan2026Member" id="nio_NioIncentivePlan2026Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ShareBasedCompensationArrangementNumberOfVestingTranches" id="nio_ShareBasedCompensationArrangementNumberOfVestingTranches" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EquityInterestToBeAcquiredPercentage" id="nio_EquityInterestToBeAcquiredPercentage" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="NumberOfSettlementTranchesForEquityAcquisition" id="nio_NumberOfSettlementTranchesForEquityAcquisition" type="xbrli:integerItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="MaximumConsiderationForEquityInterestAcquisition" id="nio_MaximumConsiderationForEquityInterestAcquisition" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ParentOwnershipInterestPercentageAfterAcquisition" id="nio_ParentOwnershipInterestPercentageAfterAcquisition" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="ChongqingChuangyuanZhiyeGroupCo.Ltd.Member" id="nio_ChongqingChuangyuanZhiyeGroupCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="OperatingLossCarryForwardsExpiringYear11" id="nio_OperatingLossCarryForwardsExpiringYear11" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="OperatingLossCarryForwardsExpiringYear12" id="nio_OperatingLossCarryForwardsExpiringYear12" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ZhonganEnergyAnhuiCo.LtdMember" id="nio_ZhonganEnergyAnhuiCo.LtdMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="ProceedsFromRelatedPartyDebtAndInterestAccrual" id="nio_ProceedsFromRelatedPartyDebtAndInterestAccrual" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DeferredProfitCurrent" id="nio_DeferredProfitCurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="DeferredProfitNoncurrent" id="nio_DeferredProfitNoncurrent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="credit" />
  <xsd:element name="CertainEquityInvestmentsInPrivateEntitiesMember" id="nio_CertainEquityInvestmentsInPrivateEntitiesMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="DeferredTaxAssetsDeferredRent" id="nio_DeferredTaxAssetsDeferredRent" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="instant" abstract="false" xbrli:balance="debit" />
  <xsd:element name="DebtInvestmentsAcquiredThroughContributionOfLongLivedAssets" id="nio_DebtInvestmentsAcquiredThroughContributionOfLongLivedAssets" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="XptHoldingAnhuiCo.Ltd.Member" id="nio_XptHoldingAnhuiCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="XptEdsHefeiCo.Ltd.Member" id="nio_XptEdsHefeiCo.Ltd.Member" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
  <xsd:element name="PaymentsToBaasUsers" id="nio_PaymentsToBaasUsers" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="ScheduleOfStatutoryIncomeTaxRatesByGeographicalAreasTableTextBlock" id="nio_ScheduleOfStatutoryIncomeTaxRatesByGeographicalAreasTableTextBlock" type="dtr-types:textBlockItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationTaxIncentivesRelatedToResearchAndDevelopmentExpendituresAmount" id="nio_EffectiveIncomeTaxRateReconciliationTaxIncentivesRelatedToResearchAndDevelopmentExpendituresAmount" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="credit" />
  <xsd:element name="EffectiveIncomeTaxRateReconciliationTaxIncentivesRelatedToResearchAndDevelopmentExpenditures" id="nio_EffectiveIncomeTaxRateReconciliationTaxIncentivesRelatedToResearchAndDevelopmentExpenditures" type="dtr-types:percentItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" />
  <xsd:element name="ValuationAllowanceDeferredTaxAssetDecreaseDueToExpirationOfTaxAttributes" id="nio_ValuationAllowanceDeferredTaxAssetDecreaseDueToExpirationOfTaxAttributes" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="false" xbrli:balance="debit" />
  <xsd:element name="ClassCommonMember" id="nio_ClassCommonMember" type="dtr-types:domainItemType" substitutionGroup="xbrli:item" nillable="true" xbrli:periodType="duration" abstract="true" />
</xsd:schema>
